Hi GINGERT
Firstly can anyone please tell me where the fuel pressure valve is.
Its on the end of the common rail.

- fuel pressure sensor on the common rail of a citroen C3 16v HDi
Common rail fuel pressure sensor is arrowed.
Secondly can anyone tell me how i can best remove the fuel rail when I cant even see it.
The Haynes Manual (click here) has a nice section on how to do this for both the 8v and the 16v engines.
I have removed all the ducting from the air intake as well as the air box but I still cant see the fuel rail. I know its under the EGR valve which I can just about see... do I need to remove this as well
Yes, remove the EGR pipe, there are some pictures
Here. You may need a new clip if yours is the original factory one. If you have the EGR out, it would be worth cleaning that too.
Remove the injector pipes from the injectors and from the rail to give better access.
This picture should help you to locate the common rail or 'accumulator rail' (arrows)

- citroen c3 common rail removal
and this one,

- Citroen C3 common rail
where I have arrowed the common rail pressure sensor and marked the location of the common rail which is mostly obscured by the flexible plastic cooling pipe.
These pictures were taken when the engine was removed from the car thanks go to RC3D for taking them.
Apparently you can get the rail off without removing the flexible pipes because they are flexible enough to be pushed out of the way.
Please please can some one offer me some good sound advice on how to get this done.
Hopefully this can give you an idea.